要保障PHP在error_log中输出日志，要确保以下设置为正确的值

php.ini中

; Common Values:
;   E_ALL (Show all errors, warnings and notices including coding standards.)
;   E_ALL & ~E_NOTICE  (Show all errors, except for notices)
;   E_ALL & ~E_NOTICE & ~E_STRICT  (Show all errors, except for notices and coding standards warnings.)
;   E_COMPILE_ERROR|E_RECOVERABLE_ERROR|E_ERROR|E_CORE_ERROR  (Show only errors)
; Default Value: E_ALL & ~E_NOTICE & ~E_STRICT & ~E_DEPRECATED
; Development Value: E_ALL
; Production Value: E_ALL & ~E_DEPRECATED & ~E_STRICT
; http://php.net/error-reporting
error_reporting = E_ALL & ~E_NOTICE & ~E_STRICT

...

; Besides displaying errors, PHP can also log errors to locations such as a
; server-specific log, STDERR, or a location specified by the error_log
; directive found below. While errors should not be displayed on productions
; servers they should still be monitored and logging is a great way to do that.
; Default Value: Off
; Development Value: On
; Production Value: On
; http://php.net/log-errors
log_errors = On

php-fpm.conf中error_log覆盖了php.ini中的设置

; Error log file
; If it's set to "syslog", log is sent to syslogd instead of being written
; in a local file.
; Note: the default prefix is /var
; Default Value: log/php-fpm.log
error_log = /var/log/php7.0-fpm.log

pool.d/www.conf中，确保开启输出（非常重要）

; Redirect worker stdout and stderr into main error log. If not set, stdout and
; stderr will be redirected to /dev/null according to FastCGI specs.
; Note: on highloaded environement, this can cause some delay in the page
; process time (several ms).
; Default Value: no
catch_workers_output = yes